Home Chemistry Scientists create a 3D-printing resin that can be reused again and again

Scientists create a 3D-printing resin that can be reused again and again

When exposed to light, anthracene and its derivative—a chemical used in producing dyes and preserving woods, among other applications—undergoes a process called photodimerization. Credit: Yokohama National University.

3D printing has moved far beyond science fiction and is now part of everyday life.

Affordable printers allow people to create everything from toys and decorations to replacement parts for broken household items.

But while many printed plastics can be recycled, one of the most advanced forms of 3D printing has faced a major environmental problem.

High-precision 3D printing methods, such as stereolithography, use ultraviolet (UV) light to harden liquid resin into solid shapes.

This process creates extremely detailed objects, even at microscopic scales. However, once the resin hardens, the chemical changes are permanent, making the material almost impossible to recycle.

Now, researchers at Yokohama National University have developed a new type of recyclable resin that may solve this issue.

Their study was published in the journal ACS Omega.

The team focused on a chemical called anthracene, which is commonly used in dyes, plastics, and wood preservatives.

Anthracene has a special property: when exposed to light, its molecules connect together to form a solid structure, but when heated, those connections can break apart again. This means the material can switch between solid and reusable liquid forms.

Professor Shoji Maruo explained that most previous “recyclable” resins still relied on irreversible chemical reactions or needed extra additives to work. Over time, those materials quickly lost quality after only a few recycling cycles. The new resin was designed to avoid those problems.

To test the material, the researchers built custom 3D-printing systems using both single-photon and two-photon lithography techniques. These methods use highly focused light to harden resin layer by layer with extremely high accuracy. The team successfully printed detailed structures, including a tiny butterfly model, showing that the new resin performs similarly to traditional high-precision resins.

One of the biggest advantages of the material is that it does not require chemical initiators, which are additives normally needed to trigger the hardening process. Instead, the resin cures through a step-by-step reaction process on its own. According to researcher Masaru Mukai, this simpler chemistry reduces contamination and improves recyclability.

The researchers demonstrated the resin’s reusability by repeatedly printing letters that spelled “YNU,” short for Yokohama National University. After printing one letter, they heated the material to erase it and reused the same resin to print the next letter. They repeated this process 10 times while maintaining good printing quality.

In another experiment, they printed a cube, melted it at 150 degrees Celsius for 15 minutes, and then reused the material to print a disk shape. The recycled resin showed only minor performance loss compared with earlier recyclable printing materials.

The researchers hope to expand the technology for larger commercial 3D printers in the future. They also plan to improve the material’s heat response and long-term durability. If successful, the invention could help make high-precision 3D printing far more sustainable while reducing plastic waste.