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Scientists turn coal ash waste into a valuable source of rare earth elements

Anuja Tripathi works in a lab developing an energy and environmentally friendly method for extracting rare earth elements from coal fly ash. Credit: Georgia Institute of Technology.

What if a waste product from coal-fired power plants could become a valuable source of materials needed for electric vehicles, smartphones, and renewable energy technologies?

Researchers at the Georgia Institute of Technology have developed a new method to recover rare earth elements from coal fly ash, a powdery waste left behind after coal is burned.

Their work could help turn billions of tons of industrial waste into a useful source of critical materials.

The research has a personal connection for lead researcher Anuja Tripathi.

Growing up in Kanpur, India, she often saw coal fly ash settling on rooftops, windows, and laundry drying outdoors.

At the time, it seemed like nothing more than an annoying pollutant.

Years later, as a postdoctoral researcher at Georgia Tech, Tripathi began to see the material in a very different way.

Coal naturally contains tiny amounts of rare earth elements, a group of metals that play a crucial role in many modern technologies.

These elements are used in electric vehicle motors, wind turbines, MRI scanners, smartphones, computer components, and military equipment because of their unique magnetic and electrical properties.

Despite their name, rare earth elements are not especially rare in the Earth’s crust. The problem is that they are usually spread out in very low concentrations, making them difficult and expensive to extract.

As demand for these materials grows, countries around the world are searching for reliable domestic sources.

Coal fly ash may offer one solution. When coal is burned, the rare earth elements become concentrated in the leftover ash. Across the United States, about 2 billion tons of coal fly ash are stored in ponds, landfills, and other disposal sites.

These storage areas can pose environmental risks because contaminants from the ash may leak into soil and groundwater. Severe weather can also spread the material into nearby communities and waterways.

Recovering valuable materials from the ash could help address both environmental and supply-chain challenges.

The Georgia Tech team developed a new extraction process that avoids many of the harsh chemicals used in traditional methods.

Instead of relying on strong acids, large amounts of water, or extremely high temperatures, the researchers use a recyclable ionic liquid, a special salt-based liquid that remains stable under demanding conditions.

The liquid pulls rare earth elements out of the ash. An electrical current is then applied, causing the metals to collect on a surface where they can be easily removed. The liquid can later be cleaned and reused, reducing waste and improving sustainability.

An interesting feature of the system is its ability to target specific elements. By adjusting the voltage, researchers can selectively recover neodymium, a highly valuable rare earth element used in powerful magnets found in electric vehicles, wind turbines, and defense technologies.

During testing, the team recovered nearly half of the available neodymium from the ash.

Although the process has so far been demonstrated on a small scale, researchers are now exploring whether it can be expanded for commercial use.

The technology could eventually be applied to other waste streams as well, including used batteries, discarded electronics, and medical waste.

If successful, materials once considered worthless trash could become an important source of the critical metals needed to power the technologies of the future.